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गर्म एलुमिना और कोक से क्लोरीन की क्रिया होती है।

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निर्जल एलुमिनियम क्लोराइड बनता है।
`Al_2O_3 + 3C + 3Cl_2 oversetDeltato 2AlCl_3 + 3CO`

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