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Assign the oxidation number to Cr in K2Cr2O7.

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Let the oxidation number of Cr be x

Sum of the oxidation number of various atoms in K2Cr2O7

= 2 × (+1) + 2x + 7 × (– 2) = 0

= 2 + 2x – 14 = 2x – 12 = 0

x = \(\frac{12}{2}\) = +6

\(\therefore\)Oxidation number of Cr in K2CrO7 = +6

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