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+1 vote
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The correct order of electron gain enthalpy is

(1) S > Se > Te > O

(2) Te > Se > S > O

(3) O > S > Se > Te

(4) S > O > Se > Te

2 Answers

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Best answer

(1) S > Se > Te > O

Oxygen is the second most electronegative element in comparison to fluorine. In group - 16 family (O, S, Se, Te), O-atom is smallest in size. So, electron density on O-atom is very high in group -16 During addition of a free electron to gaseous O-atom,

\(O(g) + e ^- \rightarrow O^- (g)\)

We have to supply a significant amount of energy (endothermic) to overcome the electrostatic repulsion between the approaching electron and O-atom of very high electron density. So, the net value of electron affinity (EA) or (negative) electron gain enthalpy \([\Delta _{eg}H\,or| \Delta _{eg}H|]\) of oxygen decreases to a higher extent in comparison to other elements of group -16 who have larger size and lower electronegativity.

So, the correct order of EA or \(|\Delta _{eg}H|\) of group −16 elements will be S > Se > Te > O

+2 votes
by (26.8k points)

(1) S > Se > Te > O

correct order of electron gain enthalpy is :-

O < S > Se > Te

⇒ S > Se > Te > O

(Oxygen shows least electron gain enthalpy due to small size of atom)

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