sec \((\frac {25\pi} 6)\) = \((\frac 2{\sqrt3})\)
∴ The question converts to sec-1\((\frac 2{\sqrt3})\)
Now,

The range of principal value of sec–1 is [0, π ] - \(\{\frac{\pi}2\}\)
and sec \((\frac{\pi}3)\) = \((\frac{2}{\sqrt3})\)
Therefore, the value of sec-1sec\((\frac{25\pi}6)\) is \(\frac{\pi}3.\)