Correct option is A. 4α = 3β
We are given that,

[\(\because\), tan(π + \(\frac{\pi}4\)) lies in III Quadrant and tangent is positive in III Quadrant]
⇒ α = tan-1(tan\(\frac{\pi}4\))
Using the property of inverse trigonometry, that is, tan -1(tan A) = A.
⇒ α = \(\frac{\pi}4\)
Now, take

[\(\because\), tan(π - \(\frac{\pi}3\)) lies in II Quadrant and tangent is negative in II Quadrant]

Using the property of inverse trigonometry, that is, tan-1(tan A) = A.

Since, the values of 4α and 3β are same, that is,
4α = 3β = π
Therefore, 4α = 3β