1. Heat is represented by the symbol ‘q’. The ‘q’ is positive, when heat is transferred from the surroundings to the system and ‘q’ is negative when heat is transferred from system to the surroundings.
Work is represented by the symbol ‘w’. The ‘w’ is positive when work is done on the system and ‘w’ is negative when work is done by the system.
2. Every substance is associated with a definite amount of energy due to its physical and chemical constitution. This is called internal energy. It is the sum of the different types of energies such as chemical, electrical, mechanical etc.