(i). In an unbiased p-n junction,
Holes diffuse from the p- region to n- region because hole concentration in p-region is more as compared to n- region.
(ii). Energy,
E = \(\frac{hc}{\lambda}\)
= \(\frac{6.6\times10^{-34}\times 3 \times 10^8}{600\times 10{-9}\times 10^{-19}}\)eV
= 2.06 eV
As E< Eg (2.8 eV),
So p-n junction cannot detect the radiation of given wavelength.