(a) No, they will be different. Actually sodium chloride (salt) is a crystalline solid while sugar is a molecular solid. They dissolve to different extent. Sodium chloride is more soluble in water compared to sugar at a given temperature. (b) Upon cooling, solid solute will slowly start separating from the solution. In general, the solubility of a solid in a liquid increases with the rise in temperature and decreases as the temperature is lowered.