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According to Fajan rules , the percentage of covalent character in an ionic compound increases . If the cation is highly charged or the cation is small and the anion is large or the cation has pseudo inert gas configuration . As a result of increased covalent character , the melting point decreases and solubility in less polar solvent increases .
Which of the following has the lowest melting point ?
A. LiCl
B. NaCl
C. KCl
D. RbCl .

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Correct Answer - A
Being predominantly covalent , LiCl has the lowest m.p.

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