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What happens when

a. Cl2 reacts with F2 in equal volume at 437 K. 

b. Br2 reacts with excess of F2.

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(a) Cl2 reacts with F2 in equal volumes at 437 K to give chlorine monofluoride ClF.

(b) Br2 reacts with excess of F2 to give bromine trifluoride BF3.

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