(i). `overset(5)(C)H_(3)overset(4)(C)H_(2)overset(3)(C)H_(2)-overset(2)(C)-=overset(1)(C)H`, pent-1-yne
(ii). `overset(5)(C)H_(3)overset(4)(C)H_(2)-overset(3)(C)-=overset(2)(C)-overset(1)(C)H_(3)`, pent-2-yne
(iii). `H_(3)overset(4)(C)-underset(CH_(3))underset(|)(overset(3)(C))-overset(2)(C)-=overset(1)(C)H`, 3-methylbut-1-yne Strutures (i) and (ii) are position isomers while strutures (i) and (iii) or (ii) and (iii) are chain isomers. Strutures (ii) and (iii) exhibit chain as well as positionn isomerism.
Note that skeleton with two side chains is not possible here because the central C atom would then have 6 bonds which is not possible:
`C-underset(C)underset(|)overset(C)overset(|)(C)-=C` (not possible)