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Hept-3-yne reacts with______ to form a diketone
A. `KMnO_4` under neutral conditions
B. alkaline `KMnO_4` at higher temperature
C. acidic ` KMnO_4`
D. all of these

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Correct Answer - A
Like alkenes, alkynes undergo hydroxylation under mild conditions. The intermediate enediol rearranges (tautomerizes) to two hydroxy ketones, which are both easily oxidized fuurther to a diketone.
image
With other reagents providing vigorous conditions oxidative cleavage occurs to produce carboxylic acids.
image

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