(a) Bauxite: Aluminium is extracted from its main ore bauxite Al2O3.2H2O. It contains 60% Al2O3.
(b) Sodium hydroxide: Sodium hydroxide dissolves bauxite to form sodium meta aluminate, removes insoluble impurities from Al2O3 by forming red mud.
(c) Cryolite: Cryolite lowers the M.P. from 2050°C to 950°C and enhances conductivity.
(d) Graphite: Acts as cathode as well as anode.