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Show that the rate of reaction is the same whether expressed in terms of the rate of consumption of any reactant or of the formation of any product.

2N2O5(g) → 4NO2(g) + O2(g)

The concentrations of reactants and products at different time intervals are given in the following table :

Concentrations of various species at different times for the reaction 2N2O5(g) → 4NO2(g) + O2(g) :

Time/s [N2O5]/M [NO2]/M [O2]/M
0 0.0300 0 0
200 0.0213 0.0174 0.00435
400 0.0152 0.0296 0.00740
600 0.0108 0.0384 0.00960

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The rate of the reaction can be expressed in terms of rate of consumption of reactants or rate of formation of products.

2N2O5(g) → 4NO2(g) + O2(g)

Consider concentrations at time t1 = 200 seconds and t2 = 400 seconds

The constant values of rate of reaction proves that the rate of the reaction may be measured in terms of concentration changes of reactants or products per unit time.

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