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Discuss the trends in the following in case of groups 16, 17 and 18 elements. 

(1) Atomic and ionic radii 

(2) Ionisation enthalpy 

(3) Electronegativity 

(4) Electron gain enthalpy

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1. Atomic and ionic radii : In groups 16, 17, 18 the atomic and ionic radii increase down the group, due to increase in the number of quantum shells. Across a period atomic or ionic radii decrease due to increase in effective nuclear charge.

2. Ionisation enthalpy : 

  • The elements of groups 16, 17 and 18 have a high ionisation enthalpy 
  • In groups 16, 17, 18 the ionisation enthalpy decreases down the group, due to increase in atomic size.

3. Electronegativity : In groups 16, 17, 18 the electronegativity decreases down the group.

4. Electron gain enthalpy : 

  • In groups 16 and 17 the electron gain enthalpy becomes less negative down the group. 
  • Group 18 elements have large positive electron gain enthalpy.

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