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How will you obtain butan-2-ol from :

(1) Propanal 

(2) butan-2-one

(3) but-2-ene?

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(1) Propanal : 

When propanal is treated with methyl magnesium iodide in the presence of dry ether, a complex is formed, which on acid hydrolysis butan 2-ol is obtained.

(2) Butan-2-one : 

When butan-2-one is hydrogenated at 413 K in the presence of catalyst finely divided nickel butan-2-ol is obtained.

(3) But-2-ene : 

When but-2-ene is passed through cold concentrated sulphuric acid, isobutyl hydrogen sulphate is formed. Isobutyl hydrogen sulphate on heating with water gives butan-2-ol.

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