Question

a. What kind of halides cannot be used to alkylate an amine :
b. Give the first amine formed from the reaction of ` I. MeCl + EtNH, II, CH_2 = CHCH_2Cl + Me_2 NH`, and III. ` PhCH_2 Cl + EtNHMe`.
c. Identify (A) to (E ).

d. Complete the following reactions :
i.

Answer 1

a. I. `3^@` halides , because they form alkenes on eleimination
II. Halides with (`beta` alkyl) group as in neopentyl halides due to steric hinderance .
III. Vinul and aryl halides [unless activated by o-or po-substituted ` EWG , e.g., (- NO_2)]`, because they do not undergo `ArSN` reaction .
b. I. `Me -NH-Et`
II.
c.
d. i.