
For a n-type semiconductor.
The electrons, from the donor impurity atoms, can move into the conduction band with very small supply of energy. The conduction band, therefore, has electrons as the majority charge carriers.
For a p-type semiconductor
In these semiconductors, a very small supply of energy can cause an electron from its valence band to jump to the acceptor energy level. The valence band, therefore, has a dominant density of holes in it. This effectively implies that the holes are the majority charge carriers in p-type semiconductor.