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एक प्रथम कोटि की अभिक्रिया में अभिकारक की सान्द्रता15 मिनट में 0.8 से घटकर 0.4 रह जाती है सान्द्रताके 0.1 M से घटकर 0.025 हो जाने में कितना समय लगेगा
A. 60 मिनट
B. 15 मिनट
C. 7.5 मिनट
D. 30 मिनट

1 Answer

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`thereforet_(1//2)=15` मिनट `thereforeK=(0.693)/(t_(1//2))`
`thereforet=(2.303xx15)/(0.693)log"(0.1)/(0.025)=30` मिनट
अन्य विधि
n अर्ध-आयु के बाद शेष बची मात्रा, `N=(N_0)/(2^n)`
या `" " 2^n=(0.1)/(0.025)=4`
`therefore" " n=2`
`therefore" " n=t/t_(t//2)" या " t=nxxt_(1//2)`
`=2xx15=30` मिनट

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