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0 votes
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in Chemistry by (66.4k points)
Hoffmann bromamide reaction involves conversion of a carboxylic acid amide into an amine with a loss of a carbon atom on treatment with aqueous sodium hypobromite. Thus Hoffmann result in shortening of a carbon chain.
`R=overset(O)overset(||)C-NH_(2)underset(NaOH)overset(Br_(2))rarrR-NH_(2)+NaBr+Na_(2)CO_(3)`
Mechanism of the reaction is :
image
Which of the following will not give Hoffmann bromamide reaction.
A. `CH_(3)-overset(O)overset(||)C-NH_(2)`
B. image
C. image
D. image

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1 Answer

0 votes
by (60.3k points)
Correct Answer - D
`2^(@)` amide do not give Hoffmann.

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