The following are the reactions for which the exponents of concentration terms are not the same as their stoichiometric coefficients in the rate equation.
`CHCl_(3)+ Cl_(2)to C Cl_(4) +HCl " "rate =k[CHCl_(3)][Cl _(2)]^(1//2)`
`CH_(3) COOC_(2) H_(5)+ H_(2)O to CH_(3) COOH+ C_(2)H_(5)OH rate =k [CHCOOC_(2)H_(5) ][H_(2)O]^(1//2)`