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Which of the following amides will not undergo Hofmann bromamide reaction?
A. `CH_3CONH_2`
B. `CH_3CONHCH_3`
C. `C_6H_5CONH_2`
D. `CH_3CH_2CONH_2`

1 Answer

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Correct Answer - B
Hofmann bromamide reaction is `R-oversetoversetO(||)C-NH_2+Br_2 + 4KOH oversetDeltato underset"Primary amine"(R NH_2) + K_2CO_3 + 2KBr + 2H_2O`
This reaction is given by primary amide only. Option (b) `CH_3CONHCH_3` is a secondary amide, so it will not undergo Hofmann bromamide reaction.

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