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Which of the following alkyl halide undergoes a nucleophilic substitution reaction via formation of a carbocation ?

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Which of the following alkyl halide undergoes a nucleophilic substitution reaction via formation of a carbocation ?
A. 1-Chloro-2-methylpropane
B. 2-Chloro-2-methylpropane
C. 2-Chlorobutane
D. 1-Chloro-3,3-dimethylpentane
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Correct Answer - B
The electron around X atom increases in C of C-X bond with the number of R-group due to +I effect of R group. Consequently, C-X bond becomes highly polarised and undergoes heterolysis.
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