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Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?

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Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?
A. Ethyl chloride
B. Isopropyl chloride.
C. Chlorobezene
D. Benzyl chloride.
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Correct Answer - D
Benzyl chloride `(C_(6)H_(5)CH_(2)Cl)` will ionise to give `C_(6)H_(5)overset(o+)(C)H_(2)`. Carbocation in the slow step according to `S_(N^(1))` mechanism. The ion will be resonance stabilised.
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