Question

What happens when ? Give equations only:
(i) chlorine reacts with `CS_(2)` in pressure of anhydrous aluminium chloride .
(ii) Chloride is heated with alcoholic KOH and aniline.
(iii) Ethyl alcohol is heated with ionic and sodium hydroxide.
(iv) Ethyl alcohol reacts with bleaching powder.
(v) Chloride is passed through ethyl alcohol.
(vi) Ethyl bromide reacts with sodium ethoxide.
(vii) Ethyl bromide reacts with silver cyanide.
(viii) Chloral is treated with aqueous sodium hydroxide.
(ix) Carbon tetrachloride is treated with hydrogen fluoride in pressure of antimony fluoride.
(x) Ethyl amine is heated with chloroform and alcoholic KOH.
(xi) Chloroform is boiled with aqueous potassium hydroxide.
(xii) Ethyl bromide is treated with alcoholic caustic soda.
(xiii) Ethyl bromine is heated with zinc.
(xiv) Methyl magnesium bromide is treated with formaldehyde followed by hydrolysis.
(xv) 2-Bromopentane is heated with alcoholic KOH.
(xvi) 2-Chloro-2- methylpropane is treated with potassium tert-butoxide in dimethyl sulphoxide.
(xvii) tertiary Butyl chloride reacts with ethylene in presence of `AICI_(3)`
(xviii) Benzene reacts with n-propyl chloride in pressure of anhydrous `AICI_(3)`

Answer 1

`(i) CS_(2) +3CI_(2) overset(AICI)(to) C CI_(4) +S_(2)CI_(2)``(i) CS_(2) +3CI_(2) overset(AICI)(to) C CI_(4) +S_(2)CI_(2)`
`(ii) C_(6)H_(5)NH_(2) +CHCI_(3)+3KOHto C_(6)H_(5)NC+3KCI +3H_(2)O`
`(iii) C_(2)H_(5)OH + 4I_(2) + 6KOH to CHI_(3)+HCOOK + 5KI +5H_(2)O`
`(iv) CaOCI_(2) +H_(2)O to Ca(OH)_(2)+CI_(2) , C_(2)H_(5)OH overset(CI_(2))underset([O])(to)`
`CH_(3)CHO overset(CI_(2))(to) C CI_(3)CHO overset(Ca(OH)_(2))(to) CHCI_(3)+ (HCOO)_(2)Ca`
`(v) C_(2)H_(5)OH overset(CI_(2))underset([O])(to) CH_(3)CHO overset(CI_(2))(to) underset(("Chloral"))(C CI_(3)CHO)`
`(vi) C_(2)H_(5) Br+ NaOC_(2)H_(5) to C_(2)H_(5)OC_(2)H_(5) +NaBr`
`(v ii)C_(2)H_(5)Br+ AgCN to C_(2)H_(5)NC +AgBr`
`(v i i i) C CI_(3) CHO + NaOH to CHCI_(3) +HCOONa`
`(i x) C CI_(4) +H_(2) F_(2) overset(SbF_(2))(to) underset(("Freon"))(C CI_(2)) F_(2) + 2HCI`
`(x ) C_(2)H_(5)NH_(2) +CHCI_(3)+3KOH to C_(2)H_(5)NC + 3KCI +3H_(2)O`
`(x i) CHCI_(3) +4KOH to HCOOK +3KCI +2H_(2)O`
`(x i i) C_(2)H_(5)Br + alc. KOH to C_(2)H_(4) + KBr + H_(2)O`
` (x i ii) 2C_(2)H_(5)Br +2Zn to (C_(2)H_(5))_(2)Zn + ZnBr_(2)`