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An ideal gas is under standard conditions. Find the diameter of the sphere within whose volume the relative fluctuation of the number of molecules is equal to  η = 1.0.10-3. What is the average number of molecules inside such a sphere?

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In a sphere of diameter d there are

where n = Loschmidt's number = No. of molecules per unit volume (1 cc) under NTP.

The relative fluctuation in this umber is 

The average number of molecules in this sphere is 1/η2 = 106

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