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Give reasons :

a. Alkali metals have low ionization energies. 

b. Inert gases have exceptionally high ionization energies.

c. Fluorine has less electron affinity than chlorine. 

d. Noble gases possess relatively large atomic size.

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a. i. Across a period, the screening effect is the same while the effective nuclear charge increases.

ii. As a result, the outer electron is held more tightly and hence, the ionization enthalpy increases across a period.

iii. Since the alkali metals are present in the group 1 of the modem periodic table, they have low ionization energies.

b. i. Across a period, the screening effect is the same and the effective nuclear charge increases.

ii. As a result, the outer electron is held more tightly and hence, the ionization enthalpy increases across a period.

iii. Inert gases are present on the extreme right of the periodic table i.e., in group 18. Also, inert gases have stable electronic configurations i.e., complete octet or duplet. 

Due to this, they are extremely stable and it is very difficult to remove electrons from their valence shell.

Hence,

Inert gases have exceptionally high ionization potential.

c. The less electron affinity of fluorine is due to its smaller size. 

Adding an electron to the 2p orbital in fluorine leads to a greater repulsion than adding an electron to the larger 3p orbital of chlorine.

Hence,

Fluorine has less electron affinity than chlorine.

d. i. Noble gases have completely filled valence shell i.e., complete octet (except He with complete duplet).

ii. Since their valence shell contains eight electrons, they experience greater electronic repulsion and this results in increased atomic size (atomic radii) of the noble gas elements. 

Hence,

Noble gases possess.

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