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An atom has two electrons in its 4s orbital. Write the values of the four quantum numbers for each of them.

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For the 4s orbital, 

4 stands for the principal quantum number n; s stands for the subshell s having the value of azimuthal quantum number, l = 0. 

In the ‘s’ subshell, there is only one orbital and has magnetic quantum number, ml = 0. 

The two electrons in this orbital have opposite spins. 

Thus, 

The four quantum numbers of two electrons in 4s orbital are :

n l ml ms
Electron 1 4 0 0 +1/2
Electron 2 4 0 0 -1/2

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