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What are the two ways in which two atomic orbitals combine to form molecular orbitals (MOs)?

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Two atomic orbitals can combine in two ways to form molecular orbitals :

i. By addition of their wave functions.

ii. By subtraction of their wave functions.

Addition of the atomic orbtials wave functions results in formation of a molecular orbital which is lower in energy than atomic orbitals and is termed as Bonding Molecular Orbital (BMO). Subtraction of the atomic orbitals results in the formation of a molecular orbital which is higher in energy than the atomic orbitals and is termed as Antibonding Molecular Orbital (AMO).

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