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How does Huckel rule help in determining the aromaticity of pyridine?

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i. Pyridine has three double bonds and 6 π electrons. 

ii. The six p orbitals containing six electrons form delocalized π molecular orbital. 

iii. The unused sp2 hybrid orbital of nitrogen containing two non-bonding electrons is as it is.

iv. According to Huckel rule, this compound is aromatic if, 4n + 2 = Number of π electrons 

4n + 2 = 6, 

∴ 4n = 6 – 2 = 4 

n = 4/4 = 1, here ‘n’ comes out to be an integer. Hence, pyridine is aromatic.

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