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Eight droplets of mercury, each of radius 1 mm, coalesce to form a single drop. Find the change in the surface energy. [Surface tension of mercury = 0.472 J/m2]

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Data : r = 1 mm = 1 × 10-3 m, T = 0.472 J/m2

Let R be the radius of the single drop formed due to the coalescence of 8 droplets of mercury.

Volume of 8 droplets = volume of the single drop as the volume of the liquid remains constant.

∴ 8 × \(\frac43\) πr3\(\frac43\) πr3

∴ 8r3 = R3

∴ 2r = R

Surface area of 8 droplets = 8 × 4πr2

Surface area of single drop = 4πR2

∴ Decrease in surface area = 8 × 4πr2 – 4πR2

= 4π(8r2 – R2

= 4π[8r2 – (2r)2

= 4π × 4r2

∴ The energy released

= surface tension × decrease in surface area

= T × 4π × 4r2 

= 0.472 × 4 × 3.142 × 4 × (1 × 10-3)2 

= 2.373 × 10-5 J

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