Correct option (d) NO2+
Explanation:
The actual geometry of the NO3- ion is trigonal planar with bond angle of 120° Hybridisation is sp2.

NO2- :Ideal geometry is trigonal planar, sp2 hybridisation with bond angle of 116°.

NO2 :ldeal geometry is trigonal planar sp2 hybridisation with bond angle of 134°.

NO2+ : Ideal geometry is linear; sp hybridisation with bond angle of 180°.
