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Nitrogen and oxygen exist as diatomic but their congeners are P4 and S8 respectively. This is due to 

(a) phosphorus and sulphur are solids 

(b) phosphorus and sulphurpolymerise as soon as they are formed 

(c) phosphorus and sulphur catenate due to the existence of d-orbitals and form strainless structures 

(d) none of these

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The correct option is (c) phosphorus and sulphur catenate due to the existence of d-orbitals and form strainless structures.

Explanation:

As nitrogen and oxygen atoms are small and highly electronegative with no vacant d-orbitals available for bonding thus, multiple bonds are formed between oxygen-oxygen and nitrogen-nitrogen atoms. 

N=N  O=O 

As the size of P and S atoms is large so multiple bonds are not strong enough, also catenation is possible due to vacant d-orbitals.

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