The correct option is (d) P (0).
Explanation:
Phosphorus (P) has electronic configuration
1s2, 2s2, 2p6. 3s2, 3p3
Therefore, no valence electron is present in the 3d-subshell.
Fe (III) has electronic configuration : 3d54s0
Cr(I) : 3d5 4so
Mn (II) :3d5 4s0