Calculation:
Let ‘P’ be the atmospheric pressure in (kPa)
‘ϕ’ be the relative humidity, ‘Pv’ be the partial pressure of the air in (KPa), ‘Pvs’ be the saturation pressure of water in (KPa), ‘ω’ be the specific humidity of air in (kg/kg of dry air)
\(ϕ = \frac{{{P_v}}}{{{P_{vs}}}} \)
\(\omega = \frac{{0.622{P_v}}}{{\left( {P - {P_v}} \right)}} \)
Calculation:
Given, ϕ = 60%, P = 100 kPa, Pvs = 4.24 kPa
\(\Rightarrow 0.6 = \frac{{{P_v}}}{{4.24}};{P_v} = 2.54\;kPa\)
\(\omega = \frac{{0.622{P_v}}}{{\left( {P - {P_v}} \right)}} = \frac{{0.622 \times 2.54}}{{\left( {100 - 2.54} \right)}}\)
ω = 0.01623 kg/kg of dry air = 16.23 g/kg of dry air
Mistake: By applying the wrong formula.
\(ϕ = \frac{{{P_{vs}}}}{{{P_v}}} \Rightarrow 0.6 = \frac{{4.24}}{{{P_v}}}\)
Pv = 7.06 KPa
\(\omega = \frac{{0.622 \times {P_v}}}{{\left( {P - {P_v}} \right)}} = \frac{{0.622 \times 7.06}}{{\left( {100 - 7.06} \right)}} = \;0.04724\;kg/kg\;of\;dry\;air\)
ω = 47.24 kg/kg of dry air
This is wrong as the partial pressure is always less than the saturation pressure. This is due to the wrong formula.