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What is e.m.f. of a cell? A cell is sending current in an external circuit. How does the terminal voltage compare with the e.m.f. of the cell? 

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When no current is drawn from a cell, i.e., when the cell is not connected to any external circuit (or is in open circuit), then the potential difference between its electrodes (or plates) is called its electromotive force, i.e., e.m.f. It is denoted by E. Emf of a cell is greater than terminal voltage.

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