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For a de Broglie wave which of the following equation is correct, 
1. λ = \(\frac{12.27}{\sqrt{V}}\)Å
2. λ = \(\frac{0.101}{\sqrt{V}}\)Å
3. λ = \(\frac{0.286}{\sqrt{V}}\)Å
4. λ = \(\frac{12400}{V}\)Å

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Correct Answer - Option 3 : λ = \(\frac{0.286}{\sqrt{V}}\)Å

CONCEPT:

Dual nature of matter:

  • According to de Broglie, the matter has a dual nature of wave-particle.
  • The wave associated with each moving particle is called matter waves.
  • ​​de Broglie wavelength associated with the particle

\(⇒ λ = \frac{h}{mv}\)   

Where, h = Planck's constant, m = mass of a particle and v = velocity of a particle

Work-Energy Theorem: 

  • The work-energy theorem states that the net work done by the forces on an object is equal to the change in its kinetic energy.

​⇒ W = ΔKE   

Where W = work done and ΔKE = change in kinetic energy

CALCULATION:

Given V volts = potential difference, charge of a proton e = 1.6×10-19 C and m = 1.67×10-31 kg

  • We know that if a charge of e coulombs is moved through a potential difference of V volts then the work done is given as,

⇒ W = eV     -----(1)

  • By work-energy theorem, the work done in accelerating a proton from rest through the electric field will be equal to the change in kinetic energy of the proton,

⇒ W = ΔKE

⇒ W = KE2 - KE1     -----(2)

Where KE1 = initial kinetic energy and KE2 = final kinetic energy

Initially, the proton is at rest so,

⇒ KE1 = 0

Final kinetic energy is given as,

\(⇒ KE_2=\frac{1}{2}× m v^2\)

So,

\(⇒ W=\frac{1}{2}× m v^2-0\)

\(⇒ W=\frac{1}{2}× m v^2\)      -----(3)

By equation 1 and equation 3,

\(⇒ eV=\frac{1}{2}× m v^2\)

\(⇒ v=\sqrt{\frac{2eV}{m}}\)     -----(4)

  • The de Broglie wavelength associated with the proton is given as,

\(⇒ λ = \frac{h}{mv}\)     -----(5)

By equation 4 and equation 5,

\(⇒ λ = \frac{h}{m}×\sqrt{\frac{m}{2eV}}\)

\(⇒ λ = \frac{h}{\sqrt{2meV}}\)

Since h = 6.6 × 10-34 J-sec

\(⇒ λ = \frac{6.6×10^{-34}}{\sqrt{2×1.67×10^{-27}×1.6×10^{-19}×V}}\)

\(\Rightarrow \lambda=\frac{0.286\times10^{-10}}{\sqrt{V}}\,m\)

\(\Rightarrow \lambda=\frac{0.286}{\sqrt{V}}\,Å\)

  • Hence, option 3 is correct.

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