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According to Bohr's atomic model, which of the following can't be the value of angular momentum of the electron:
1. \(\frac{h}{\pi}\)
2. \(\frac{h}{4\pi}\)
3. \(\frac{2h}{\pi}\)
4. \(\frac{3h}{\pi}\)

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Correct Answer - Option 2 : \(\frac{h}{4\pi}\)

CONCEPT:

Bohr's Atomic Model:

  • Bohr proposed a model for hydrogen atom which is also applicable for some lighter atoms in which a single electron revolves around a stationary nucleus of positive charge Ze (called hydrogen-like atom).

Bohr's model is based on the following postulates:

  • He postulated that an electron in an atom can move around the nucleus in certain circular stable orbits without emitting radiations.
  • Bohr found that the magnitude of the electron's angular momentum is quantized i.e.

\(⇒ L = m{v_n}\;{r_n} = n\left( {\frac{h}{{2\pi }}} \right)\)

Where n = 1, 2, 3, ..... each value of n corresponds to a permitted value of the orbit radius, rn = Radius of nth orbit, vn = corresponding speed, and h = Planck's constant

EXPLANATION:

According to Bohr's atomic model, 
  • The magnitude of the electron's angular momentum is quantized and is given as,

\(⇒ L = n\left( {\frac{h}{{2\pi }}} \right)\)

For option 1,

\(⇒ n\left( {\frac{h}{{2\pi }}} \right)=\frac{h}{\pi}\)

⇒ n = 2     -----(1)

For option 2,

\(⇒ n\left( {\frac{h}{{2\pi }}} \right)=\frac{h}{4\pi}\)

⇒ n = 0.5     -----(2)

For option 3,

\(⇒ n\left( {\frac{h}{{2\pi }}} \right)=\frac{2h}{\pi}\)

⇒ n = 4     -----(3)

For option 4,

\(⇒ n\left( {\frac{h}{{2\pi }}} \right)=\frac{3h}{\pi}\)

⇒ n = 6     -----(4)

  • Since the angular momentum is quantized so the value of n can only be an integer.
  • For \(\frac{h}{4\pi}\), the value of n is a decimal number so \(\frac{h}{4\pi}\) can't be the value of the angular momentum of the electron.
  • Hence, option 2 is correct.

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