Correct Answer - Option 3 : 1000 times
Concept
We know, pH is defined as the negative logarithm of [H]+ ion.
So,
pH = -log10 [H+]
-log10 [H+] = pH
[H+] = 10 -pH
Calculation
pH of water samples are
pH = 4 ⇒[H+] = 10 - 4
pH = 7 ⇒ [H+] = 10-7
Comparing Both [H+]
\(\frac{{{{\left[ {{H^ + }} \right]}_I}}}{{{{\left[ {{H^ + }} \right]}_{II}}}} = \frac{{{{10}^{ -4}}}}{{{{10}^{ - 7}}}} = {10^{3}} = 1000\)
Hence, first sample is 1000 times acidic than second sample.