The correct option is (a) \(\cfrac{4Kq}{3b^2}\)

Given side of cube is b then diagonal length of cube is r = \(\cfrac{\sqrt3b}2\)
the electric field AB will be effective and other will be cancle out
E = \(\cfrac{Kq}{r^2}\)
\(\because\) r = \(\cfrac{\sqrt3b}2\)
E = \(\cfrac{Kq}{(\cfrac{\sqrt3}2b)^2}\)
E = \(\cfrac{4Kq}{3b^2}\)