When N2 goes to N+2 the N-N bond distance Increases, and when O2 goes to O2+ the O-O bond distance decreases;
Explanation:
The molecular configurations of N2 and O2 are as follows
:. Bond order in N2 = 1/2 (8 - 2) = 3 and bond order in N2+ =1/2 (7-2) = 2.5
Thus conversion of N2 to N2+ decreases bond order (from 3 to 2.5) and hence increases the N-N bond distance.
Bond order in O2 - (8 - 4) = 2
and bond order in O2+ = 1/2(8- 3)= 2.5
Thus conversion of O2+ to O2+increases bond order (from 2 to 2.5) hence decreases O-O bond distance.