In H2O2 , oxidation number of oxygen is - 1 , on the basis of electronic configuration, oxidation number of oxygen is -2 or + 2.
In H2O2, oxidation number of oxygen -1, so it can be increased upto +2 and decreased upto -2. Hence, due to this reason it acts as reducing and oxidising agents.
Reducing agent : H2O2 → 2H+ + O2 + 2e-
Oxidising agent (i) Acidic medium
H2O2 → 2H+ + 2e- → 2H2O
(ii) Basic medium H2O2 + 2e- → 2OH-