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What is the pH of the solution when 0.20 moles of HCI is added to one litre of a solution containing : 

(i) 1M each of acetic acid and acetate ion 

(ii) 0. 1 M each of acetic acid and acetate ion 

Assume the total volume is one litre. Ka for acetic acid = 1.8 x 10-5

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(CH3COOH no doubt gives H+ but being weak acid as well as in presence of HCl does not dissociate appreciably and thus, H+ from CH3COOH may be neglected)

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