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Give reasons in one or two sentences "Ammonium chloride is acidic in liquid ammonia solvent."

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Give reasons in one or two sentences "Ammonium chloride is acidic in liquid ammonia solvent."

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It is due to self-ionisation of NH3. The reaction is

2NH3 ⇄ NH+4 + NH-2

Thus, on addition of NH4CI the concentration of NI+4 radical increases and therefore, NH4CI acts as an acid in liquid NH3.

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