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A scarlet compound A is treated with conc. HNO3 to give a chocolate brown precipitate B. The precipitate is filtered and the filtrate is neutralised with NaOH. Addition of KI to the resulting solution gives a yellow ppt. C. The brown ppt" B on warming with conc. HNO3 in the presence of Mn(NO3)2 produces a pink coloured solution due to the formation of D. Identify A,B, C and D. Write the reaction sequence.

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Filterate Pb(NO3)2 is neutralised with NaOH and on reaction with KI to give yellow ppt. of pbl2

PbO2 on warming with conc. HNO3 in presence of Mn(NO3)2 produced pink coloured solution due to formation of Pb(MnO4)2D

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