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e- deficient species are PH3, B2H6, CCl4, NH3, LiH, BCl3 = ?

(a) PH3, B2H6

(b) CCl4, NH3

(c) BC13, B2H6

(d) LiH, BCl3

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(c) BC13, B2H6

In BCl3, Boron has 3 valence electrons, after forming bonds with chlorine electrons around it increases to 6, but it still is short of 2 electrons. In B2H6, B forms 3C -2e-bond and has less number of electrons. Hence, these are electron deficient species.

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