The correct option (B) cos–1(1/3)
Explanation:

Let O is on vertex of cube and vector(OA, OB, OC) are directions with x, y, z axis.
also OA = OB = OC = a
diagonals are vector(AL, BM, CN,OP)
∴ vector AL = (– a, a, a)
vector BM = (a, – a, a)
Angle between vector AL & vector BM is θ
∴ cos θ = [vector(|AL ∙ BM|)/vector(|AL| |BM|)] = [{|– a2 – a2 + a2|}/{√(3a2) √(3a2)}]
∴ cosθ = (1/3) ⇒ θ = cos–1(1/3).