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Mixture (s) showing positive deviation from Raoult’s law at 35°C is (are) 

(A) carbon tetrachloride + methanol 

(B) carbon disulphide + acetone 

(C) benzene + toluene 

(D) phenol + aniline

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Best answer

(A) carbon tetrachloride + methanol 

(B) carbon disulphide + acetone 

Benzene + toluene will form ideal solution. 

Phenol + aniline will show negative deviation.

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