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Given a and b values for Xe, Kr, Ar and He are

Xe Kr Ar He
a(L2bar/mol2) 4.1 2.3 1.3 0.03
b(L/mol) 0.1 0.04 0.03 0.02

The gas with highest Tc is

(1) Xe

(2) Kr

(3) Ar

(4) He

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