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Andrew's Isotherms.

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Andrew's Isotherms : Isotherms of CO2 at different temperatures

• At A (13.1°C) CO2 exists as gas

• On increasing pressure, at B liquefaction starts.

• At C, liquefaction is complete.

• After that, increase in pressure has little effect on volume, since liquids have low compressibility. 

• Above 30.98°C, gas cannot be liquified howsoever high pressure may be applied.

• Point P (30.98°C) is the critical temperature.

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